If you like the Hotmail service but not the "too cute" domain, why not sign up for an outlook.com email account? Exactly the same interface, and unlike "Hotmail" or even "Live.com" the domain comes across as professional.
Or, as said, mail.com. I don't know if the company behind mail.com is reliable and if the service is trustworthy and stable. I never tried them. But in terms of domains they have some very professional options (mail.com, email.com, I think post.com too...)
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